Division SCOPE
United Kingdom
These BAT conclusions cover certain industrial activities specified in Sections 4.2(a) and 4.2(c) of Annex I to Directive 2010/75/EU, namely the production of chlor-alkali chemicals (chlorine, hydrogen, potassium hydroxide and sodium hydroxide) by the electrolysis of brine.
In particular, these BAT conclusions cover the following processes and activities:
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the storage of salt;
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the preparation, purification and resaturation of brine;
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the electrolysis of brine;
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the concentration, purification, storage and handling of sodium/potassium hydroxide;
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the cooling, drying, purification, compression, liquefaction, storage and handling of chlorine;
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the cooling, purification, compression, storage and handling of hydrogen;
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the conversion of mercury cell plants to membrane cell plants;
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the decommissioning of mercury cell plants;
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the remediation of chlor-alkali production sites.
These BAT conclusions do not address the following activities or processes:
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the electrolysis of hydrochloric acid for the production of chlorine;
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the electrolysis of brine for the production of sodium chlorate; this is covered by the BAT reference document on Large Volume Inorganic Chemicals – Solids and Others Industry (LVIC-S);
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the electrolysis of molten salts for the production of alkali or alkaline earth metals and chlorine; this is covered by the BAT reference document on Non-ferrous Metals Industries (NFM);
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the production of specialities such as alcoholates, dithionites and alkali metals by using alkali metal amalgam produced with the mercury cell technique;
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the production of chlorine, hydrogen or sodium/potassium hydroxide by processes other than electrolysis.
These BAT conclusions do not address the following aspects of chlor-alkali production as they are covered by the BAT reference document on Common Waste Water and Waste Gas Treatment/Management Systems in the Chemical Sector (CWW);
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the treatment of waste water in a downstream treatment plant;
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environmental management systems;
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noise emissions.
Other reference documents which are of relevance for the activities covered by these BAT conclusions are the following:
| Reference document | Subject |
|---|---|
| Common Waste Water and Waste Gas Treatment/Management Systems in the Chemical Sector BREF (CWW) | Common waste water and waste gas treatment/management systems |
| Economics and Cross-Media Effects (ECM) | Economics and cross-media effects of techniques |
| Emissions from Storage (EFS) | Storage and handling of materials |
| Energy Efficiency (ENE) | General aspects of energy efficiency |
| Industrial Cooling Systems (ICS) | Indirect cooling with water |
| Large Combustion Plants (LCP) | Combustion plants with a rated thermal input of 50 MW or more |
| General Principles of Monitoring (MON) | General aspects of emissions and consumption monitoring |
| Waste Incineration (WI) | Waste incineration |
| Waste Treatments Industries (WT) | Waste treatment |