Division 5 Monitoring of emissions
United Kingdom
BAT 7: BAT is to monitor emissions to air and water by using monitoring techniques in accordance with EN standards with at least the minimum frequency given below. If EN standards are not available, BAT is to use ISO, national or other international standards that ensure the provision of data of an equivalent scientific quality.
| Monitoring encompasses both continuous and periodic monitoring as indicated. | ||||||
| Environmental medium | Substance(s) | Sampling point | Method | Standard(s) | Minimum monitoring frequency | Monitoring associated with |
|---|---|---|---|---|---|---|
| Air | Chlorine and chlorine dioxide, expressed as Cl2 f1 | Outlet of chlorine absorption unit | Electrochemical cells | No EN or ISO standard available | Continuous | — |
| Absorption in a solution, with subsequent analysis | No EN or ISO standard available | Yearly (at least three consecutive hourly measurements) | BAT 8 | |||
| Water | Chlorate | Where the emission leaves the installation | Ion chromatography | EN ISO 10304–4 | Monthly | BAT 14 |
| Chloride | Brine purge | Ion chromatography or flow analysis | EN ISO 10304–1 or EN ISO 15682 | Monthly | BAT 12 | |
| Free chlorine | Close to the source | Reduction potential | No EN or ISO standard available | Continuous | — | |
| Where the emission leaves the installation | Free chlorine | EN ISO 7393–1 or –2 | Monthly | BAT 13 | ||
| Halogenated organic compound | Brine purge | Adsorbable organically-bound halogens (AOX) | Annex A to EN ISO 9562 | Yearly | BAT 15 | |
| Mercury | Outlet of the mercury treatment unit | Atomic absorption spectrometry or atomic fluorescence spectrometry | EN ISO 12846 or EN ISO 17852 | Daily | BAT 3 | |
| Sulphate | Brine purge | Ion chromatography | EN ISO 10304–1 | Yearly | — | |
| Relevant heavy metals (e.g. nickel, copper) | Brine purge | Inductively-coupled plasma optical emission spectrometry or inductively-coupled plasma mass spectrometry | EN ISO 11885 or EN ISO 17294-2 | Yearly | — | |
Annotations
Footnotes
- f1
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Monitoring encompasses both continuous and periodic monitoring as indicated.