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Annex Watch list of substances for Union-wide monitoring as set out in Article 8b of Directive 2008/105/EC

United Kingdom

Original text. Later amendments are not shown.

Chemical Abstracts Service.

European Union number.

To ensure comparability of results from different Member States, all substances shall be monitored in whole water samples.

Extraction methods:

  • LLE – liquid liquid extraction

  • SPE – solid-phase extraction

Analytical methods:

  • LC-MS-MS – Liquid chromatography (tandem) triple quadrupole mass spectrometry.

Sulfamethoxazole and trimethoprim shall be analysed together in the same samples but reported as individual concentrations.

Venlafaxine and O-desmethylvenlafaxine shall be analysed together in the same samples but reported as individual concentrations.

The azole compounds shall be analysed together in the same samples but reported as individual concentrations.

Name of substance/group of substancesCAS numberf1 EU numberf2 Indicative analytical methodf3 f4 Maximum acceptable method detection limit (ng/l)
Metaflumizone139968-49-3604-167-6LLE-LC-MS-MS or SPE–LC-MS-MS65
Amoxicillin26787-78-0248-003-8SPE-LC-MS-MS78
Ciprofloxacin85721-33-1617-751-0SPE-LC-MS-MS89
Sulfamethoxazolef5 723-46-6211-963-3SPE-LC-MS-MS100
Trimethoprim 738-70-5212-006-2SPE-LC-MS-MS100

Venlafaxine and

O-desmethylvenlafaxinef6

93413-69-5

93413-62-8

618-944-2

700-516-2

SPE-LC-MS-MS6
Azole compounds f7 SPE-LC-MS-MS

Clotrimazole

Fluconazole

Imazalil

Ipconazole

Metconazole

Miconazole

Penconazole

Prochloraz

Tebuconazole

Tetraconazole

23593-75-1

86386-73-4

35554-44-0

125225-28-7

125116-23-6

22916-47-8

66246-88-6

67747-09-5

107534-96-3

112281-77-3

245-764-8

627-806-0

252-615-0

603-038-1

603-031-3

245-324-5

266-275-6

266-994-5

403-640-2

407-760-6

20

250

800

44

29

200

1 700

161

240

1 900

Dimoxystrobin149961-52-4604-712-8SPE-LC-MS-MS32
Famoxadone131807-57-3603-520-1SPE-LC-MS-MS8,5

Annotations

Footnotes

f1

Chemical Abstracts Service.

f2

European Union number.

f3

To ensure comparability of results from different Member States, all substances shall be monitored in whole water samples.

f4

Extraction methods:

  • LLE – liquid liquid extraction

  • SPE – solid-phase extraction

Analytical methods:

  • LC-MS-MS – Liquid chromatography (tandem) triple quadrupole mass spectrometry.

f5

Sulfamethoxazole and trimethoprim shall be analysed together in the same samples but reported as individual concentrations.

f6

Venlafaxine and O-desmethylvenlafaxine shall be analysed together in the same samples but reported as individual concentrations.

f7

The azole compounds shall be analysed together in the same samples but reported as individual concentrations.