{
  "url": "https://openlegislation.uk/eu-directive-2012-18/annex-I/part-2",
  "json_url": "https://openlegislation.uk/eu-directive-2012-18/annex-I/part-2.json",
  "legislation": "eudr/2012/18",
  "legislation_title": "Directive 2012/18/EU of the European Parliament and of the Council of 4 July 2012 on the control of major-accident hazards involving dangerous substances, amending and subsequently repealing Council Directive 96/82/EC (Text with EEA relevance)",
  "legislation_url": "https://openlegislation.uk/eu-directive-2012-18",
  "path": "annex/I/part/2",
  "kind": "part",
  "number": "2",
  "heading": "Named dangerous substances",
  "text": "The CAS number is shown only for indication.\nProvided that the mixture in the absence of sodium hypochlorite would not be classified as Aquatic Acute Category 1 [H400].\nColumn 1\nCAS number\nColumn 2\nColumn 3\nQualifying quantity (tonnes) for the application of\nDangerous substances\nLower-tier requirements\nUpper-tier requirements\n1.\nAmmonium nitrate (see note 13)\n—\n5 000\n10 000\n2.\nAmmonium nitrate (see note 14)\n—\n1 250\n5 000\n3.\nAmmonium nitrate (see note 15)\n—\n350\n2 500\n4.\nAmmonium nitrate (see note 16)\n—\n10\n50\n5.\nPotassium nitrate (see note 17)\n—\n5 000\n10 000\n6.\nPotassium nitrate (see note 18)\n—\n1 250\n5 000\n7.\nArsenic pentoxide, arsenic (V) acid and/or salts\n1303-28-2\n1\n2\n8.\nArsenic trioxide, arsenious (III) acid and/or salts\n1327-53-3\n0,1\n9.\nBromine\n7726-95-6\n20\n100\n10.\nChlorine\n7782-50-5\n10\n25\n11.\nNickel compounds in inhalable powder form: nickel monoxide, nickel dioxide, nickel sulphide, trinickel disulphide, dinickel trioxide\n—\n1\n12.\nEthyleneimine\n151-56-4\n10\n20\n13.\nFluorine\n7782-41-4\n10\n20\n14.\nFormaldehyde (concentration ≥ 90 %)\n50-00-0\n5\n50\n15.\nHydrogen\n1333-74-0\n5\n50\n16.\nHydrogen chloride (liquefied gas)\n7647-01-0\n25\n250\n17.\nLead alkyls\n—\n5\n50\n18.\nLiquefied flammable gases, Category 1 or 2 (including LPG) and natural gas (see note 19)\n—\n50\n200\n19.\nAcetylene\n74-86-2\n5\n50\n20.\nEthylene oxide\n75-21-8\n5\n50\n21.\nPropylene oxide\n75-56-9\n5\n50\n22.\nMethanol\n67-56-1\n500\n5 000\n23.\n4, 4′-Methylene bis (2-chloraniline) and/or salts, in powder form\n101-14-4\n0,01\n24.\nMethylisocyanate\n624-83-9\n0,15\n25.\nOxygen\n7782-44-7\n200\n2 000\n26.\n2,4 -Toluene diisocyanate\n584-84-9\n10\n100\n2,6 -Toluene diisocyanate\n91-08-7\n27.\nCarbonyl dichloride (phosgene)\n75-44-5\n0,3\n0,75\n28.\nArsine (arsenic trihydride)\n7784-42-1\n0,2\n1\n29.\nPhosphine (phosphorus trihydride)\n7803-51-2\n0,2\n1\n30.\nSulphur dichloride\n10545-99-0\n1\n31.\nSulphur trioxide\n7446-11-9\n15\n75\n32.\nPolychlorodibenzofurans and polychlorodibenzodioxins (including TCDD), calculated in TCDD equivalent (see note 20)\n—\n0,001\n33.\nThe following CARCINOGENS or the mixtures containing the following carcinogens at concentrations above 5 % by weight:\n4-Aminobiphenyl and/or its salts, Benzotrichloride, Benzidine and/or salts, Bis (chloromethyl) ether, Chloromethyl methyl ether, 1,2-Dibromoethane, Diethyl sulphate, Dimethyl sulphate, Dimethylcarbamoyl chloride, 1,2-Dibromo-3-chloropropane, 1,2-Dimethylhydrazine, Dimethylnitrosamine, Hexamethylphosphoric triamide, Hydrazine, 2- Naphthylamine and/or salts, 4-Nitrodiphenyl, and 1,3 Propanesultone\n—\n0,5\n2\n34.\nPetroleum products and alternative fuels\n(a) gasolines and naphthas,\n(b) kerosenes (including jet fuels),\n(c) gas oils (including diesel fuels, home heating oils and gas oil blending streams)\n(d) heavy fuel oils\n(e) alternative fuels serving the same purposes and with similar properties as regards flammability and environmental hazards as the products referred to in points (a) to (d)\n—\n2 500\n25 000\n35.\nAnhydrous Ammonia\n7664-41-7\n50\n200\n36.\nBoron trifluoride\n7637-07-2\n5\n20\n37.\nHydrogen sulphide\n7783-06-4\n5\n20\n38.\nPiperidine\n110-89-4\n50\n200\n39.\nBis(2-dimethylaminoethyl) (methyl)amin\n3030-47-5\n50\n200\n40.\n3-(2-Ethylhexyloxy)propylamin\n5397-31-9\n50\n200\n41.\nMixtures of sodium hypochlorite classified as Aquatic Acute Category 1 [H400] containing less than 5 % active chlorine and not classified under any of the other hazard categories in Part 1 of Annex I.\n200\n500\n42.\nPropylamine (see note 21)\n107-10-8\n500\n2 000\n43.\nTert-butyl acrylate (see note 21)\n1663-39-4\n200\n500\n44.\n2-Methyl-3-butenenitrile (see note 21)\n16529-56-9\n500\n2 000\n45.\nTetrahydro-3,5-dimethyl-1,3,5,-thiadiazine-2-thione (Dazomet) (see note 21)\n533-74-4\n100\n200\n46.\nMethyl acrylate (see note 21)\n96-33-3\n500\n2 000\n47.\n3-Methylpyridine (see note 21)\n108-99-6\n500\n2 000\n48.\n1-Bromo-3-chloropropane (see note 21)\n109-70-6\n500\n2 000",
  "extent": "E+W+S+N.I.",
  "status": null,
  "version": "current",
  "annotations": [
    {
      "type": "footnote",
      "label": "f1",
      "text": "The CAS number is shown only for indication."
    },
    {
      "type": "footnote",
      "label": "f2",
      "text": "Provided that the mixture in the absence of sodium hypochlorite would not be classified as Aquatic Acute Category 1 [H400]."
    }
  ],
  "outstanding_effects": [],
  "provenance": {
    "source": "legislation.gov.uk",
    "source_url": "https://www.legislation.gov.uk/eudr/2012/18/annex/I/part/2",
    "retrieved_at": "2026-11-01T15:21:57.246231+00:00"
  },
  "licence": "Open Government Licence v3.0",
  "licence_url": "https://www.nationalarchives.gov.uk/doc/open-government-licence/version/3/",
  "attribution": "Contains public sector information licensed under the Open Government Licence v3.0. Source: legislation.gov.uk, The National Archives."
}