# Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 (Text with EEA relevance), Division 1: Part 1: Criteria for the selection of precautionary statements

Extent: E+W+S+N.I.

Table 6.1
Precautionary statements — General
Code
General precautionary statements
Hazard class
Hazard category
Conditions for use
(1)
(2)
(3)
(4)
(5)
P101
If medical advice is needed, have product container or label at hand.
as appropriate
Consumer products
P102
Keep out of reach of children.
as appropriate
Consumer products
P103
Read carefully and follow all instructions.
as appropriate
Consumer products – omit where P202 is used
Table 6.2
Precautionary statements — Prevention
Code
Prevention precautionary statements
Hazard class
Hazard category
Conditions for use
(1)
(2)
(3)
(4)
(5)
P201
Obtain special instructions before use.
Explosives (section 2.1)
Unstable explosive
Germ cell mutagenicity (section 3.5)
1A,1B, 2
Consumer products – omit where P202 is used
Carcinogenicity (section 3.6)
1A,1B, 2
Reproductive toxicity (section 3.7)
1A,1B, 2
Reproductive toxicity — effects on or via lactation (section 3.7)
Additional category
P202
Do not handle until all safety precautions have been read and understood.
Flammable gases (section 2.2)
A, B (chemically unstable gases)
Germ cell mutagenicity (section 3.5)
1A,1B, 2
Carcinogenicity (section 3.6)
1A,1B, 2
Reproductive toxicity (section 3.7)
1A,1B, 2
Reproductive toxicity, effects on or via lactation (section 3.7)
Additional category
P210
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
Explosives (section 2.1)
Divisions 1.1, 1.2, 1.3, 1.4, 1.5
Flammable gases (section 2.2)
1A, 1B, 2
Aerosols (section 2.3)
1, 2, 3
Flammable liquids (section 2.6)
1, 2, 3
Flammable solids (section 2.7)
1, 2
Self-reactive substances and mixtures (section 2.8)
Types A, B, C, D, E, F
Pyrophoric liquids (section 2.9)
1
Pyrophoric solids (section 2.10)
1
Oxidising liquids (section 2.13)
1, 2, 3
Oxidising solids (section 2.14)
1, 2, 3
Organic peroxides (section 2.15)
Types A, B, C, D, E, F
Desensitised explosives (section 2.17)
1, 2, 3, 4
P211
Do not spray on an open flame or other ignition source.
Aerosols (section 2.3)
1, 2
P212
Avoid heating under confinement or reduction of the desensitising agent.
Desensitised explosives (section 2.17)
1, 2, 3, 4
P220
Keep away from clothing and other combustible materials.
Oxidising gases (Section 2.4)
1
Oxidising liquids (Section 2.13)
1, 2, 3
Oxidising solids (Section 2.14)
1, 2, 3
P222
Do not allow contact with air.
Flammable gases (section 2.2)
Pyrophoric gas
if emphasis of the hazard statement is deemed necessary .
Pyrophoric liquids (section 2.9)
1
Pyrophoric solids (section 2.10)
1
P223
Do not allow contact with water.
Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12)
1, 2
—
if emphasis of the hazard statement is deemed necessary
P230
Keep wetted with …
Explosives (section 2.1)
Divisions 1.1, 1.2, 1.3, 1.5
Manufacturer/supplier to specify appropriate material
for substances and mixtures which are wetted, diluted, dissolved or suspended with a phlegmatiser in order to suppress their explosive properties
Desensitised explosives (section 2.17)
1, 2, 3, 4
Manufacturer/supplier to specify appropriate material
P231
Handle and store contents under inert gas/…
Pyrophoric liquids (Section 2.9)
1
… Manufacturer/supplier to specify appropriate liquid or gas if ‘ inert gas ’ is not appropriate.
Pyrophoric solids (Section 2.10)
1
Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12)
1, 2, 3
—
if the substance or mixture reacts readily with moisture in air.
… Manufacturer/supplier to specify appropriate liquid or gas if ‘ inert gas ’ is not appropriate.
P232
Protect from moisture.
Substances and mixtures which, in contact with water, emit flammable gases (section 2.12)
1, 2, 3
P233
Keep container tightly closed.
Flammable liquids (section 2.6)
1, 2, 3
if the liquid is volatile and may generate an explosive atmosphere
Pyrophoric liquids (section 2.9)
1
Pyrophoric solids (section 2.10)
1
Desensitised explosives (section 2.17)
1, 2, 3, 4
Acute toxicity – inhalation (section 3.1)
1, 2, 3
if the chemical is volatile and may generate a hazardous atmosphere
Specific target organ toxicity – single exposure; respiratory tract irritation (section 3.8)
3
Specific target organ toxicity – single exposure; narcotic effects (section 3.8)
3
P234
Keep only in original packaging.
Explosives (Section 2.1)
Divisions 1.1, 1.2, 1.3, 1.4, 1.5
Self-reactive substances and mixtures (Section 2.8)
Types A, B, C, D, E, F
Organic peroxides (Section 2.15)
Types A, B, C, D, E, F
Corrosive to metals (Section 2.16)
1
P235
Keep cool.
Flammable liquids (Section 2.6)
1, 2, 3
—
for flammable liquids category 1 and other flammable liquids that are volatile and may generate an explosive atmosphere
Self-reactive substances and mixtures (Section 2.8)
Types A, B, C, D, E, F
—
may be omitted if P411 is given on the label
Self-heating substances and mixtures (Section 2.11)
1, 2
—
may be omitted if P413 is given on the label
Organic peroxides (Section 2.15)
Types A, B, C, D, E, F
—
may be omitted if P411 is given on the label
P240
Ground and bond container and receiving equipment.
Explosives (Section 2.1)
Divisions 1.1, 1.2, 1.3, 1.4, 1.5
—
if the explosive is electrostatically sensitive
Flammable liquids (Section 2.6)
1, 2, 3
—
if the liquid is volatile and may generate an explosive atmosphere
Flammable solids (Section 2.7)
1, 2
—
if the solid is electrostatically sensitive
Self-reactive substances and mixtures (Section 2.8)
Types A,B,C, D, E, F
—
if electrostatically sensitive and able to generate an explosive atmosphere
Organic peroxides (Section 2.15)
P241
Use explosion-proof [electrical/ventilating/lighting/…] equipment.
Flammable liquids (Section 2.6)
1, 2, 3
if the liquid is volatile and may generate an explosive atmosphere.
text in square brackets may be used to specify specific electrical, ventilating, lighting or other equipment if necessary and as appropriate.
Flammable solids (Section 2.7)
1, 2
if dust clouds can occur.
text in square brackets may be used to specify specific electrical, ventilating, lighting or other equipment if necessary and as appropriate.
P242
Use non-sparking tools.
Flammable liquids (Section 2.6)
1, 2, 3
—
if the liquid is volatile and may generate an explosive atmosphere and if the minimum ignition energy is very low. (This applies to substances and mixtures where the ignition energy is < 0,1 mJ, e.g. carbon disulphide).
P243
Take action to prevent static discharges.
Flammable liquids (Section 2.6)
1, 2, 3
—
if the liquid is volatile and may generate an explosive atmosphere.
P244
Keep valves and fittings free from oil and grease.
Oxidising gases (section 2.4)
1
P250
Do not subject to grinding/shock/friction …
Explosives (Section 2.1)
Unstable explosives and divisions 1.1, 1.2, 1.3, 1.4, 1.5
—
if the explosive is mechanically sensitive
… Manufacturer/supplier to specify applicable rough handling.
P251
Do not pierce or burn, even after use.
Aerosols (section 2.3)
1, 2, 3
P260
Do not breathe dust/fume/gas/mist/vapours/spray.
Acute toxicity — inhalation (section 3.1)
1, 2
Manufacturer/supplier to specify applicable conditions.
Specific target organ toxicity — single exposure (section 3.8)
1, 2
Specific target organ toxicity — repeated exposure (section 3.9)
1, 2
Skin corrosion (section 3.2)
1A, 1B, 1C
Specify do not breathe dusts or mists.
if inhalable particles of dusts or mists may occur during use.
Reproductive toxicity — effects on or via lactation (section 3.7)
Additional category
P261
Avoid breathing dust/fume/gas/mist/vapours/spray.
Acute toxicity — inhalation (Section 3.1)
3, 4
—
may be omitted if P260 is given on the label
Manufacturer/supplier to specify applicable conditions.
Respiratory sensitisation (Section 3.4)
1, 1A, 1B
Skin sensitisation (Section 3.4)
1, 1A, 1B
Specific target organ toxicity — single exposure; respiratory tract irritation (Section 3.8)
3
Specific target organ toxicity — single exposure; narcotic effects (Section 3.8)
3
P262
Do not get in eyes, on skin, or on clothing.
Acute toxicity — dermal (section 3.1)
1, 2
P263
Avoid contact during pregnancy and while nursing.
Reproductive toxicity — effects on or via lactation (Section 3.7)
Additional category
P264
Wash … thoroughly after handling.
Acute toxicity — oral (section 3.1)
1, 2, 3, 4
Manufacturer/supplier to specify parts of the body to be washed after handling.
Acute toxicity — dermal (section 3.1)
1, 2
Skin corrosion (section 3.2)
1A, 1B, 1C
Skin irritation (section 3.2)
2
Eye irritation (section 3.3)
2
Reproductive toxicity — effects on or via lactation (section 3.7)
Additional category
Specific target organ toxicity — single exposure (section 3.8)
1, 2
Specific target organ toxicity — repeated exposure (section 3.9)
1
P270
Do not eat, drink or smoke when using this product.
Acute toxicity — oral (section 3.1)
1, 2, 3, 4
Acute toxicity — dermal (section 3.1)
1, 2
Reproductive toxicity — effects on or via lactation (section 3.7)
Additional category
Specific target organ toxicity — single exposure (section 3.8)
1, 2
Specific target organ toxicity — repeated exposure (section 3.9)
1
P271
Use only outdoors or in a well-ventilated area.
Acute toxicity — inhalation (section 3.1)
1, 2, 3, 4
Specific target organ toxicity — single exposure; respiratory tract irritation (section 3.8)
3
Specific target organ toxicity — single exposure; narcosis (section 3.8)
3
P272
Contaminated work clothing should not be allowed out of the workplace.
Skin sensitisation (section 3.4)
1, 1A, 1B
P273
Avoid release to the environment.
Hazardous to the aquatic environment — acute aquatic hazard (section 4.1)
1
if this is not the intended use.
Hazardous to the aquatic environment — long-term aquatic hazard (section 4.1)
1, 2, 3, 4
P280
Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/…
Explosives (section 2.1)
Unstable explosive and divisions 1.1, 1.2, 1.3, 1.4, 1.5
Manufacturer/supplier to specify the appropriate type of personal protective equipment.
Flammable gases (section 2.2)
Pyrophoric gas
Flammable liquids (section 2.6)
1, 2, 3
Flammable solids (section 2.7)
1, 2
Self-reactive substances and mixtures (section 2.8)
Types A, B, C, D, E, F
Pyrophoric liquids (section 2.9)
1
Pyrophoric solids (section 2.10)
1
Self-heating substances and mixtures (section 2.11)
1, 2
Substances and mixtures which, in contact with water, emit flammable gases (section 2.12)
1, 2, 3
Oxidizing liquids (section 2.13)
1, 2, 3
Oxidizing solids (section 2.14)
1, 2, 3
Organic peroxides (section 2.15)
Types A, B, C, D, E, F
Desensitised explosives (section 2.17)
1, 2, 3, 4
Acute toxicity – dermal (section 3.1)
1, 2, 3, 4
Specify protective gloves/clothing.
Manufacturer/supplier may further specify type of equipment where appropriate.
Skin corrosion (section 3.2)
1A, 1B, 1C
Specify protective gloves/clothing and eye/face protection.
Manufacturer/supplier may further specify type of equipment where appropriate.
Skin irritation (section 3.2)
2
Specify protective gloves.
Manufacturer/supplier may further specify type of equipment where appropriate.
Skin sensitisation (section 3.4)
1, 1A, 1B
Serious eye damage (section 3.3)
1
Specify eye/face protection.
Manufacturer/supplier may further specify type of equipment where appropriate.
Eye irritation (section 3.3)
2
Germ cell mutagenicity (section 3.5)
1A, 1B, 2
Manufacturer/supplier to specify the appropriate type of personal protective equipment.
Carcinogenicity (section 3.6)
1A, 1B, 2
Reproductive toxicity (section 3.7)
1A, 1B, 2
P282
Wear cold insulating gloves and either face shield or eye protection.
Gases under pressure (Section 2.5)
Refrigerated liquefied gas
P283
Wear fire resistant or flame retardant clothing.
Oxidising liquids (Section 2.13)
1
Oxidising solids (Section 2.14)
1
P284
[In case of inadequate ventilation] wear respiratory protection.
Acute toxicity — inhalation (Section 3.1)
1, 2
—
text in square brackets may be used if additional information is provided with the chemical at the point of use that explains what type of ventilation would be adequate for safe use.
Manufacturer/supplier to specify equipment.
Respiratory sensitisation (Section 3.4)
1, 1A, 1B
P231 + P232
Handle and store contents under inert gas/…
Protect from moisture.
Pyrophoric liquids (Section 2.9)
1
… Manufacturer/supplier to specify the appropriate liquid or gas if ‘ inert gas ’ is not appropriate.
Pyrophoric solids (Section 2.10)
1
Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12)
1, 2, 3
—
if the substance or mixture reacts readily with moisture in air.
… Manufacturer/supplier to specify appropriate liquid or gas if ‘ inert gas ’ is not appropriate.
Table 6.3
Precautionary statements — Response
Code
Response precautionary statements
Hazard class
Hazard category
Conditions for use
(1)
(2)
(3)
(4)
(5)
P301
IF SWALLOWED:
Acute toxicity – oral (section 3.1)
1, 2, 3, 4
Skin corrosion (section 3.2)
1, 1A, 1B, 1C
Aspiration Hazard (section 3.10)
1
P302
IF ON SKIN:
Pyrophoric liquids (section 2.9)
1
Pyrophoric solids (section 2.10)
1
Substances and mixtures which, in contact with water, emit flammable gases (section 2.12)
1, 2
Acute toxicity – dermal (section 3.1)
1, 2, 3, 4
Skin irritation (section 3.2)
2
Skin sensitisation (section 3.4)
1, 1A, 1B
P303
IF ON SKIN (or hair):
Flammable liquids (section 2.6)
1, 2, 3
Skin corrosion (section 3.2)
1A, 1B, 1C
P304
IF INHALED:
Acute toxicity — inhalation (section 3.1)
1, 2, 3, 4
Skin corrosion (section 3.2)
1A, 1B, 1C
Respiratory sensitisation (section 3.4)
1, 1A, 1B
Specific target organ toxicity — single exposure; respiratory tract irritation (section 3.8)
3
Specific target organ toxicity — single exposure; narcosis (section 3.8)
3
P305
IF IN EYES:
Skin corrosion (section 3.2)
1A, 1B, 1C
Serious eye damage/eye irritation (section 3.3)
1
Eye irritation (section 3.3)
2
P306
IF ON CLOTHING:
Oxidising liquids (section 2.13)
1
Oxidising solids (section 2.14)
1
P308
IF exposed or concerned:
Germ cell mutagenicity (section 3.5)
1A, 1B, 2
Carcinogenicity (section 3.6)
1A, 1B, 2
Reproductive toxicity (section 3.7)
1A, 1B, 2
Reproductive toxicity — effects on or via lactation (section 3.7)
Additional category
Specific target organ toxicity, single exposure (section 3.8)
1, 2
P310
Immediately call a POISON CENTER/doctor/…
Acute toxicity — oral (section 3.1)
1, 2, 3
…Manufacturer/supplier to specify the appropriate source of emergency medical advice.
Acute toxicity — dermal (section 3.1)
1, 2
Acute toxicity — inhalation (section 3.1)
1, 2
Skin corrosion (section 3.2)
1A, 1B, 1C
Serious eye damage/eye irritation (section 3.3)
1
Aspiration hazard (section 3.10)
1
P311
Call a POISON CENTER/doctor/…
Acute toxicity — inhalation (section 3.1)
3
…Manufacturer/supplier to specify the appropriate source of emergency medical advice.
Respiratory sensitisation (section 3.4)
1, 1A, 1B
Specific target organ toxicity — single exposure (section 3.8)
1, 2
P312
Call a POISON CENTRE/doctor/… if you feel unwell.
Acute toxicity — oral (Section 3.1)
4
… Manufacturer/supplier to specify the appropriate source of emergency medical advice.
Acute toxicity — dermal (Section 3.1)
3, 4
Acute toxicity — inhalation (Section 3.1)
4
Specific target organ toxicity — single exposure; respiratory tract irritation (Section 3.8)
3
Specific target organ toxicity — single exposure; narcotic effects (Section 3.8)
3
P313
Get medical advice/attention.
Skin irritation (section 3.2)
2, 3
Eye irritation (section 3.3)
2
Skin sensitisation (section 3.4)
1, 1A, 1B
Germ cell mutagenicity (section 3.5)
1A, 1B, 2
Carcinogenicity (section 3.6)
1A, 1B, 2
Reproductive toxicity (section 3.7)
1A, 1B, 2
Reproductive toxicity — effects on or via lactation (section 3.7)
Additional category
P314
Get medical advice/attention if you feel unwell.
Specific target organ toxicity — repeated exposure (section 3.9)
1, 2
P315
Get immediate medical advice/attention.
Gases under pressure (section 2.5)
Refrigerated liquefied gas
P320
Specific treatment is urgent (see … on this label).
Acute toxicity — inhalation (Section 3.1)
1, 2
—
if immediate administration of antidote is required.
… Reference to supplemental first aid instruction.
P321
Specific treatment (see … on this label).
Acute toxicity — oral (Section 3.1)
1, 2, 3
—
if immediate administration of antidote is required.
… Reference to supplemental first aid instruction.
Acute toxicity, dermal (Section 3.1)
1, 2, 3, 4
—
if immediate measures such as specific cleansing agent are advised.
… Reference to supplemental first aid instruction.
Acute toxicity — inhalation (Section 3.1)
3
—
if immediate specific measures are required.
… Reference to supplemental first aid instruction.
Skin corrosion (Section 3.2)
1, 1A, 1B, 1C
… Reference to supplemental first aid instruction.
Manufacturer/supplier may specify a cleansing agent if appropriate.
Skin irritation (Section 3.2)
2
Skin sensitisation (Section 3.4)
1, 1A, 1B
Specific target organ toxicity — single exposure (Section 3.8)
1
—
if immediate measures are required.
… Reference to supplemental first aid instruction.
P330
Rinse mouth.
Acute toxicity — oral (section 3.1)
1, 2, 3, 4
Skin corrosion (section 3.2)
1A, 1B, 1C
P331
Do NOT induce vomiting.
Skin corrosion (section 3.2)
1A, 1B, 1C
Aspiration hazard (section 3.10)
1
P332
If skin irritation occurs:
Skin irritation (section 3.2)
2
may be omitted if P333 is given on the label.
P333
If skin irritation or rash occurs:
Skin sensitisation (section 3.4)
1, 1A, 1B
P334
Immerse in cool water [or wrap in wet bandages].
Pyrophoric liquids (Section 2.9)
1
—
text in square brackets to be used for pyrophoric liquids and solids
Pyrophoric solids (Section 2.10)
1
Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12)
1, 2
Use only ‘ immerse in cool water. ’ Text in square brackets should not be used.
P335
Brush off loose particles from skin.
Pyrophoric solids (section 2.10)
1
Substances and mixtures which, in contact with water, emit flammable gases (section 2.12)
1, 2
P336
Thaw frosted parts with lukewarm water. Do not rub affected area.
Gases under pressure (section 2.5)
Refrigerated liquefied gas
P337
If eye irritation persists:
Eye irritation (section 3.3)
2
P338
Remove contact lenses, if present and easy to do. Continue rinsing.
Skin corrosion (section 3.2)
1A, 1B, 1C
Serious eye damage/eye irritation (section 3.3)
1
Eye irritation (section 3.3)
2
P340
Remove person to fresh air and keep comfortable for breathing.
Acute toxicity — inhalation (section 3.1)
1, 2, 3, 4
Skin corrosion (section 3.2)
1A, 1B, 1C
Respiratory sensitisation (section 3.4)
1, 1A, 1B
Specific target organ toxicity — single exposure; respiratory tract irritation (section 3.8)
3
Specific target organ toxicity — single exposure; narcosis (section 3.8)
3
P342
If experiencing respiratory symptoms:
Respiratory sensitisation (section 3.4)
1, 1A, 1B
P351
Rinse cautiously with water for several minutes.
Skin corrosion (section 3.2)
1A, 1B, 1C
Serious eye damage/eye irritation (section 3.3)
1
Eye irritation (section 3.3)
2
P352
Wash with plenty of water/…
Acute toxicity — dermal (section 3.1)
1, 2, 3, 4
…Manufacturer/supplier may specify a cleansing agent if appropriate, or may recommend an alternative agent in exceptional cases if water is clearly inappropriate.
Skin irritation (section 3.2)
2
Skin sensitisation (section 3.4)
1, 1A, 1B
P353
Rinse skin with water [or shower].
Flammable liquids (Section 2.6)
1, 2, 3
—
text in square brackets to be included where the manufacturer/supplier considers it appropriate for the specific chemical.
Skin corrosion (Section 3.2)
1, 1A, 1B, 1C
P360
Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
Oxidising liquids (section 2.13)
1
Oxidising solids (section 2.14)
1
P361
Take off immediately all contaminated clothing.
Flammable liquids (section 2.6)
1, 2, 3
Acute toxicity — dermal (section 3.1)
1, 2, 3
Skin corrosion (section 3.2)
1A, 1B, 1C
P362
Take off contaminated clothing.
Acute toxicity, dermal (section 3.1)
4
Skin irritation (section 3.2)
2
Skin sensitisation (section 3.4)
1, 1A, 1B
P363
Wash contaminated clothing before reuse.
Skin corrosion (section 3.2)
1A, 1B, 1C
P364
And wash it before reuse.
Acute toxicity, dermal (section 3.1)
1, 2, 3, 4
Skin irritation (section 3.2)
2
Skin sensitisation (section 3.4)
1, 1A, 1B
P370
In case of fire:
Explosives (section 2.1)
Unstable explosives and divisions 1.1, 1.2, 1.3, 1.4, 1.5
Oxidising gases (section 2.4)
1
Flammable liquids (section 2.6)
1, 2, 3
Flammable solids (section 2.7)
1, 2
Self-reactive substances and mixtures (section 2.8)
Types A, B, C, D, E, F
Pyrophoric liquids (section 2.9)
1
Pyrophoric solids (section 2.10)
1
Substances and mixtures which, in contact with water, emit flammable gases (section 2.12)
1, 2, 3
Oxidising liquids (section 2.13)
1, 2, 3
Oxidising solids (section 2.14)
1, 2, 3
Organic Peroxides (section 2.15)
Types A, B, C, D, E, F
Desensitised explosives (section 2.17)
1, 2, 3
P371
In case of major fire and large quantities:
Oxidising liquids (section 2.13)
1
Oxidising solids (section 2.14)
1
Desensitised explosives (section 2.17)
4
P372
Explosion risk.
Explosives (Section 2.1)
Unstable explosives and Divisions 1.1, 1.2, 1.3, and 1.5
Division 1.4
—
except for explosives of division 1.4 (compatibility group S) in transport packaging.
Self-reactive substances and mixtures (Section 2.8)
Type A
Organic peroxides (Section 2.15)
Type A
P373
DO NOT fight fire when fire reaches explosives.
Explosives (Section 2.1)
Unstable explosives and Divisions 1.1, 1.2, 1.3, 1.5
Division 1.4
—
except for explosives of division 1.4 (compatibility group S) in transport packaging.
Self-reactive substances and mixtures (Section 2.8)
Type A
Organic peroxides (Section 2.15)
Type A
P375
Fight fire remotely due to the risk of explosion.
Explosives (section 2.1)
Division 1.4
for explosives of division 1.4 (compatibility group S) in transport packaging.
Self-reactive substances and mixtures (section 2.8)
Type B
Oxidising liquids (section 2.13)
1
Oxidising solids (section 2.14)
1
Organic peroxides (section 2.15)
Type B
Desensitised explosives (section 2.17)
1, 2, 3, 4
P376
Stop leak if safe to do so.
Oxidising gases (section 2.4)
1
P377
Leaking gas fire: Do not extinguish, unless leak can be stopped safely.
Flammable gases (section 2.2)
1A, 1B, 2
P378
Use … to extinguish.
Flammable liquids (Section 2.6)
1, 2, 3
—
if water increases risk
… Manufacturer/supplier to specify appropriate media
Flammable solids (Section 2.7)
1, 2
Self-reactive substances and mixtures (Section 2.8)
Types B, C, D, E, F
Pyrophoric liquids (Section 2.9)
1
Pyrophoric solids (Section 2.10)
1
Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12)
1, 2, 3
Oxidising liquids (Section 2.13)
1, 2, 3
Oxidising solids (Section 2.14)
1, 2, 3
Organic peroxides (Section 2.15)
Types B, C, D, E, F
P380
Evacuate area.
Explosives (section 2.1)
Unstable explosives and Divisions 1.1, 1.2, 1.3, 1.4, 1.5
Self-reactive substances and mixtures (section 2.8)
Types A, B
Oxidising liquids (section 2.13)
1
Oxidising solids (section 2.14)
1
Organic peroxides (section 2.15)
Types A, B
Desensitised explosives (section 2.17)
1, 2, 3, 4
P381
In case of leakage, eliminate all ignition sources
Flammable gases (section 2.2)
1A, 1B, 2
P390
Absorb spillage to prevent material damage.
Corrosive to metals (section 2.16)
1
P391
Collect spillage.
Hazardous to the aquatic environment – acute aquatic hazard (section 4.1)
1
Hazardous to the aquatic environment – long-term aquatic hazard (section 4.1)
1, 2
P301 + P310
IF SWALLOWED: Immediately call a POISON CENTER/doctor/…
Acute toxicity — oral (section 3.1)
1, 2, 3
…Manufacturer/supplier to specify the appropriate source of emergency medical advice.
Aspiration hazard (section 3.10)
1
P301 + P312
IF SWALLOWED: Call a POISON CENTER/doctor/… if you feel unwell
Acute toxicity – oral (section 3.1)
4
… Manufacturer/supplier to specify the appropriate source of emergency medical advice
P302 + P334
IF ON SKIN: Immerse in cool water or wrap in wet bandages.
Pyrophoric liquids (Section 2.9)
1
P302 + P352
IF ON SKIN: Wash with plenty of water/…
Acute toxicity — dermal (section 3.1)
1, 2, 3, 4
…Manufacturer/supplier may specify a cleansing agent if appropriate, or may recommend an alternative agent in exceptional cases if water is clearly inappropriate.
Skin irritation (section 3.2)
2
Skin sensitisation (section 3.4)
1, 1A, 1B
P304 + P340
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
Acute toxicity — inhalation (section 3.1)
1, 2, 3, 4
Skin corrosion (section 3.2)
1A, 1B, 1C
Respiratory sensitisation (section 3.4)
1, 1A, 1B
Specific target organ toxicity — single exposure; respiratory tract irritation (section 3.8)
3
Specific target organ toxicity — single exposure; narcosis (section 3.8)
3
P306 + P360
IF ON CLOTHING: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
Oxidising liquids (section 2.13)
1
Oxidising solids (section 2.14)
1
P308 + P311
IF exposed or concerned: Call a POISON CENTER/doctor/…
Specific target organ toxicity — single exposure (section 3.8)
1, 2
…Manufacturer/supplier to specify the appropriate source of emergency medical advice.
P308 + P313
IF exposed or concerned: Get medical advice/attention.
Germ cell mutagenicity (section 3.5)
1A, 1B, 2
Carcinogenicity (section 3.6)
1A, 1B, 2
Reproductive toxicity (section 3.7)
1A, 1B, 2
Reproductive toxicity — effects on or via lactation (section 3.7)
Additional category
P332 + P313
If skin irritation occurs: Get medical advice/attention.
Skin irritation (Section 3.2)
2
—
may be omitted when P333 + P313 is given on the label.
P333 + P313
If skin irritation or rash occurs: Get medical advice/attention.
Skin sensitisation (section 3.4)
1, 1A, 1B
P336 + P315
Thaw frosted parts with lukewarm water. Do not rub affected area. Get immediate medical advice/attention.
Gases under pressure (Section 2.5)
Refrigerated liquefied gas
P337 + P313
If eye irritation persists: Get medical advice/attention.
Eye irritation (section 3.3)
2
P342 + P311
If experiencing respiratory symptoms: Call a POISON CENTER/doctor/…
Respiratory sensitisation (section 3.4)
1, 1A, 1B
…Manufacturer/supplier to specify the appropriate source of emergency medical advice.
P361 + P364
Take off immediately all contaminated clothing and wash it before reuse.
Acute toxicity, dermal (section 3.1)
1, 2, 3
P362 + P364
Take off contaminated clothing and wash it before reuse.
Acute toxicity, dermal (section 3.1)
4
Skin irritation (section 3.2)
2
Skin sensitisation (section 3.4)
1, 1A, 1B
P370 + P376
In case of fire: Stop leak if safe to do so.
Oxidizing gases (section 2.4)
1
P370 + P378
In case of fire: Use … to extinguish.
Flammable liquids (Section 2.6)
1, 2, 3
—
if water increases risk.
… Manufacturer/sup-plier to specify appropriate media.
Flammable solids (Section 2.7)
1, 2
Self-reactive substances and mixtures (Section 2.8)
Types C, D, E, F
Pyrophoric liquids (Section 2.9)
1
Pyrophoric solids (Section 2.10)
1
Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12)
1, 2, 3
Oxidising liquids (Section 2.13)
1, 2, 3
Oxidising solids (Section 2.14)
1, 2, 3
Organic peroxides (Section 2.15)
Types C, D, E, F
P301 + P330 + P331
IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
Skin corrosion (Section 3.2)
1, 1A, 1B, 1C
P302 + P335 + P334
IF ON SKIN: Brush off loose particles from skin. Immerse in cool water [or wrap in wet bandages].
Pyrophoric solids (Section 2.10)
1
—
text in square brackets to be used for pyrophoric solids
Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12)
1, 2
—
use only ‘ Immerse in cold water ’ . Text in square brackets should not be used.
P303 + P361 + P353
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower].
Flammable liquids (Section 2.6)
1, 2, 3
—
text in square brackets to be included where the manufacturer/supplier considers it appropriate for the specific chemical.
Skin corrosion (Section 3.2)
1, 1A, 1B, 1C
P305 + P351 + P338
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Skin corrosion (Section 3.2)
1, 1A, 1B, 1C
Serious eye damage/eye irritation (Section 3.3)
1
Eye irritation (Section 3.3)
2
P370 + P380 + P375
In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion.
Explosives (section 2.1)
Division 1.4
for explosives of division 1.4 (compatibility group S) in transport packaging
Desensitised explosives (section 2.17)
1, 2, 3
P371 + P380 + P375
In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion.
Oxidising liquids (section 2.13)
1
Oxidising solids (section 2.14)
1
Desensitised explosives (section 2.17)
4
P370 + P372 + P380 + P373
In case of fire: Explosion risk. Evacuate area. DO NOT fight fire when fire reaches explosives
Explosives (Section 2.1)
Unstable explosives and divisions 1.1, 1.2, 1.3, 1.5
Division 1.4
—
except for explosives of division 1.4 (compatibility group S) in transport packaging.
Self-reactive substances and mixtures (Section 2.8)
Type A
Organic peroxides (Section 2.15)
Type A
P370 + P380 + P375 + [P378]
In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion. [Use … to extinguish].
Self-reactive substances and mixtures (Section 2.8)
Type B
—
text in square brackets to be used if water increases risk.
… Manufacturer/supplier to specify appropriate media.
Organic peroxides (Section 2.15)
Type B
Table 6.4
Precautionary statements — Storage
Code
Storage precautionary statements
Hazard class
Hazard category
Conditions for use
(1)
(2)
(3)
(4)
(5)
P401
Store in accordance with …
Explosives (section 2.1)
Unstable explosives and Divisions 1.1, 1.2, 1.3, 1.4, 1.5
… Manufacturer/supplier to specify local/regional/national/international regulations as applicable.
Desensitised explosives (section 2.17)
1, 2, 3, 4
P402
Store in a dry place.
Substances and mixtures which, in contact with water, emit flammable gases (section 2.12)
1, 2, 3
P403
Store in a well-ventilated place.
Flammable gases (section 2.2)
1A, 1B, 2
Oxidising gases (section 2.4)
1
Gases under pressure (section 2.5)
Compressed gas
Liquefied gas
Refrigerated liquefied gas
Dissolved gas
Flammable liquids (section 2.6)
1, 2, 3
for flammable liquids Category 1 and other flammable liquids that are volatile and may generate an explosive atmosphere.
Self-reactive substances and mixtures (section 2.8)
Types A, B, C, D, E, F
except for temperature controlled self-reactive substances and mixtures or organic peroxides because condensation and consequent freezing may take place.
Organic peroxides (section 2.15)
Acute toxicity – inhalation (section 3.1)
1, 2, 3
if the substance or mixture is volatile and may generate a hazardous atmosphere.
Specific target organ toxicity – single exposure; respiratory tract irritation (section 3.8)
3
Specific target organ toxicity – single exposure; narcotic effects (section 3.8)
3
P404
Store in a closed container.
Substances and mixtures which, in contact with water, emit flammable gases (section 2.12)
1, 2, 3
P405
Store locked up.
Acute toxicity — oral (section 3.1)
1, 2, 3
Acute toxicity — dermal (section 3.1)
1, 2, 3
Acute toxicity — inhalation (section 3.1)
1, 2, 3
Skin corrosion (section 3.2)
1A, 1B, 1C
Germ cell mutagenicity (section 3.5)
1A, 1B, 2
Carcinogenicity (section 3.6)
1A, 1B, 2
Reproductive toxicity (section 3.7)
1A, 1B, 2
Specific target organ toxicity — single exposure (section 3.8)
1, 2
Specific target organ toxicity — single exposure; respiratory tract irritation (section 3.8)
3
Specific target organ toxicity — single exposure; narcosis (section 3.8)
3
Aspiration hazard (section 3.10)
1
P406
Store in a corrosion-resistant/… container with a resistant inner liner.
Corrosive to metals (Section 2.16)
1
—
may be omitted if P234 is given on the label
… Manufacturer/supplier to specify other compatible materials.
P407
Maintain air gap between stacks or pallets.
Self-heating substances and mixtures (Section 2.11)
1, 2
P410
Protect from sunlight.
Aerosols (section 2.3)
1,2, 3
Gases under pressure (section 2.5)
Compressed gas
Liquefied gas
Dissolved gas
—
may be omitted for gases filled in transportable gas cylinders in accordance with packing instruction P200 of the UN RTDG, Model Regulations, unless those gases are subject to (slow) decomposition or polymerisation
Self-heating substances and mixtures (section 2.11)
1, 2
Organic peroxides (section 2.15)
Types A, B, C, D, E, F
P411
Store at temperatures not exceeding … °C/… °F.
Self-reactive substances and mixtures (Section 2.8)
Types A, B, C, D, E, F
—
if temperature control is required (according to Annex I, Section 2.8.2.4 or 2.15.2.3) or if otherwise deemed necessary.
… Manufacturer/supplier to specify temperature using the applicable temperature scale.
Organic peroxides (Section 2.15)
Types A, B, C, D, E, F
P412
Do not expose to temperatures exceeding 50 °C/ 122 °F.
Aerosols (Section 2.3)
1, 2, 3
Manufacturer/supplier to use applicable temperature scale.
P413
Store bulk masses greater than … kg/… lbs at temperatures not exceeding … °C/… °F.
Self-heating substances and mixtures (Section 2.11)
1, 2
… Manufacturer/supplier to specify mass and temperature using applicable scale.
P420
Store separately.
Self-reactive substances and mixtures (Section 2.8)
Types A, B, C, D, E, F
Self-heating substances and mixtures (Section 2.11)
1,2
Oxidising liquids (Section 2.13)
1
Oxidising solids (Section 2.14)
1
Organic peroxides (Section 2.15)
Types A,B,C,D,E,F
P402 + P404
Store in a dry place. Store in a closed container.
Substances and mixtures which, in contact with water, emit flammable gases (section 2.12)
1, 2, 3
P403 + P233
Store in a well-ventilated place. Keep container tightly closed.
Acute toxicity — inhalation (Section 3.1)
1, 2, 3
—
if the substance or mixture is volatile and may generate a hazardous atmosphere.
Specific target organ toxicity — single exposure; respiratory tract irritation (Section 3.8)
3
Specific target organ toxicity — single exposure; narcosis (Section 3.8)
3
P403 + P235
Store in a well-ventilated place. Keep cool.
Flammable liquids (Section 2.6)
1, 2, 3
—
for flammable liquids Category 1 and other flammable liquids that are volatile and may generate an explosive atmosphere.
P410 + P403
Protect from sunlight. Store in a well-ventilated place.
Gases under pressure (Section 2.5)
Compressed gas
—
P410 may be omitted for gases filled in transportable gas cylinders in accordance with packing instruction P200 of the UN RTDG, unless those gases are subject to (slow) decomposition or polymerisation.
Liquefied gas
Dissolved gas
P410 + P412
Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F.
Aerosols (Section 2.3)
1, 2, 3
Manufacturer/ supplier to use applicable temperature scale.
Table 6.5
Precautionary statements — Disposal
Code
Disposal precautionary statements
Hazard class
Hazard category
Conditions for use
(1)
(2)
(3)
(4)
(5)
P501
Dispose of contents/container to …
Flammable liquids (section 2.6)
1, 2, 3
… in accordance with local/regional/national/international regulation (to be specified).
Manufacturer/supplier to specify whether disposal requirements apply to contents, container or both.
Self-reactive substances and mixtures (section 2.8)
Types A, B, C, D, E, F
Substances and mixtures which, in contact with water, emit flammable gases (section 2.12)
1, 2, 3
Oxidising liquids (section 2.13)
1, 2, 3
Oxidising solids (section 2.14)
1, 2, 3
Organic peroxides (section 2.15)
Types A, B, C, D, E, F
Desensitised explosives (section 2.17)
1, 2, 3, 4
Acute toxicity – oral (section 3.1)
1, 2, 3, 4
Acute toxicity – dermal (section 3.1)
1, 2, 3, 4
Acute toxicity – inhalation (section 3.1)
1, 2, 3
Skin corrosion (section 3.2)
1, 1A, 1B, 1C
Respiratory sensitisation (section 3.4)
1, 1A, 1B
Skin sensitisation (section 3.4)
1, 1A, 1B
Germ cell mutagenicity (section 3.5)
1A, 1B, 2
Carcinogenicity (section 3.6)
1A, 1B, 2
Reproductive toxicity (section 3.7)
1A, 1B, 2
Specific target organ toxicity – single exposure (section 3.8)
1, 2
Specific target organ toxicity – single exposure; respiratory tract irritation (section 3.8)
3
Specific target organ toxicity – single exposure; narcotic effects (section 3.8)
3
Specific target organ toxicity – repeated exposure (section 3.9)
1, 2
Aspiration hazard (section 3.10)
1
Hazardous to the aquatic environment – acute aquatic hazard (section 4.1)
1
Hazardous to the aquatic environment – chronic aquatic hazard (section 4.1)
1, 2, 3, 4
P502
Refer to manufacturer or supplier for information on recovery or recycling
Hazardous to the ozone layer (Section 5.1)
1
P503
Refer to manufacturer/ supplier/… for information on disposal/recovery/ recycling
Explosives (section 2.1)
Unstable explosives and Divisions 1.1, 1.2, 1.3, 1.4, 1.5
… Manufacturer/supplier to specify appropriate source of information in accordance with local/regional/national/international regulations as applicable.

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Source: https://www.legislation.gov.uk/eur/2008/1272/annex/IV/division/1 (the official version)
Page: https://openlegislation.uk/eu-regulation-2008-1272/annex-IV/division-1
Contains public sector information licensed under the Open Government Licence v3.0. Source: legislation.gov.uk, The National Archives.