{
  "url": "https://openlegislation.uk/fertilisers-sampling-and-analysis-regulations-northern-ireland-1996/schedule-2/part-I/chapter-25j./paragraph-4",
  "json_url": "https://openlegislation.uk/fertilisers-sampling-and-analysis-regulations-northern-ireland-1996/schedule-2/part-I/chapter-25j./paragraph-4.json",
  "legislation": "nisr/1996/513",
  "legislation_title": "Fertilisers (Sampling and Analysis) Regulations (Northern Ireland) 1996",
  "legislation_url": "https://openlegislation.uk/fertilisers-sampling-and-analysis-regulations-northern-ireland-1996",
  "path": "schedule/2/part/I/chapter/25j./paragraph/4",
  "kind": "paragraph",
  "number": "4",
  "heading": "REAGENTS",
  "text": "Dilute hydrochloric acid solution (HCl), about 6 M\n4.1 See Method 25d (4.1).\nCopper solution (70 mg/l) in 1.5 M hydrochloric acid\n4.2 Dissolve 275 mg of copper sulfate (CuSO4 5H2O) weighed to within 0.1 mg in 250 ml of the 6 M hydrochloric acid solution (4.1) in a 1000 ml volumetric flask. Make up to volume with water and mix thoroughly.\nAscorbic acid solution (50 g/l)\n4.3 Dissolve 50 g of ascorbic acid (C6H8O6) in water in a 1000 ml volumetric flask. Make up to volume with water, mix thoroughly and keep in a refrigerator.\nn-butyl acetate\n4.4\nAmmonium thiocyanate solution, 0.2 M\n4.5 Dissolve 15.224 g of NH4SCN in water in a 1000 ml volumetric flask. Make up to volume with water; mix thoroughly and store in a dark-coloured bottle.\nStannous chloride solution (50 g/l) in 2 M hydrochloric acid\n4.6 This solution must be perfectly clear and prepared immediately before use. Very pure stannous chloride must be used otherwise the solution will not be clear.\nTo prepare 100 ml of solution, dissolve 5 g of SnCl2.2H2O in 35 ml of 6 M HCl solution (4.1). Add 10 ml of the copper solution (4.2). Make up to volume with water and mix thoroughly.\nMolybdenum calibration solutions\n4.7 Molybdenum stock solution (500 mg/ml)\n4.7.1 Dissolve 0.920 g of ammonium molybdate [(NH4)6Mo7O24.4H2O]; weighed to within 0.1 mg in the 6 M hydrochloric acid (4.1) in a 1 litre volumetric flask. Make up to volume with that solution and mix thoroughly.\nmolybdenum intermediate solution (25 mg/ml)\n4.7.2 Place 25 ml of the stock solution (4.7.1) in a 500 ml volumetric flask. Make up to volume with 6M hydrochloric acid (4.1) and mix thoroughly.\nMolybdenum working solution (2.5 mg/ml)\n4.7.3 Place 10 ml of the intermediate solution (4.7.2) in a 100 ml volumetric flask. Make up to volume with 6 M hydrochloric acid (4.1) and mix thoroughly.",
  "extent": null,
  "status": null,
  "version": "current",
  "annotations": [],
  "outstanding_effects": [],
  "provenance": {
    "source": "legislation.gov.uk",
    "source_url": "https://www.legislation.gov.uk/nisr/1996/513/schedule/2/part/I/chapter/25j./paragraph/4",
    "retrieved_at": "2026-10-29T02:32:40.012993+00:00"
  },
  "licence": "Open Government Licence v3.0",
  "licence_url": "https://www.nationalarchives.gov.uk/doc/open-government-licence/version/3/",
  "attribution": "Contains public sector information licensed under the Open Government Licence v3.0. Source: legislation.gov.uk, The National Archives."
}