# The Plastic Materials and Articles in Contact with Food (England) Regulations 2006, Part 2: Incomplete List of Additives Used in the Manufacture of Plastic Materials and Articles (Being Additives to which Paragraph 5 of Part 3 of this Schedule Applies)


Item
1
PM/REFNo.
2
CAS No
3
Name
4
Restrictions and specifications
1
30180
002180-18-9
Acetic acid, manganese salt
SML(T) = 0.6 mg/kg (9) (expressed as manganese)
2
31520
061167-58-6
Acrylic acid, 2-tert-butyl- 6-(3-tert- butyl- 2-hydroxy-5-methylbenzyl)-4-methylphenyl ester
SML = 6 mg/kg
3
31920
000103-23-1
Adipic acid, bis (2-ethylhexyl) ester
SML = 18 mg/kg (1)
4
34230
Alkyl (C8-C22) sulphonic acids
SML = 6 mg/kg
4A
34650
151841-65-5
Aluminium hydroxybis [2,2'-methylenebis (4,6-di-tert-butylphenyl)] phospate
SML = 5 mg/kg
5
35760
001309-64-4
Antimony trioxide
SML = 0.02 mg/kg (expressed as anti-monium and analytical tolerance included)
6
36720
017194-00-2
Barium hydroxide
SML(T) = 1 mg/kg (11) (expressed as barium)
7
36800
010022-31-8
Barium nitrate
SML(T) = 1 mg/kg (11) (expressed as barium)
7A
38000
000553-54-8
Benzoic acid, lithium salt
SML(T) = 0.6 mg/kg (8) (expressed as lithium)
8
38240
000119-61-9
Benzophenone
SML = 0.6 mg/kg
9
38560
007128-64-5
2,5-Bis (5-tert-butyl-2-benzoxazolyl) thiophene
SML = 0.6 mg/kg
10
38700
063397-60-4
Bis (2-carbobutoxyethyl) tin- bis (isooctyl mercaptoacetate)
SML = 18 mg/kg
11
38800
032687-78-8
N,N'-Bis (3-(3,5-di-tert-butyl-4-hydroxyphenyl) propionyl) hydrazide
SML = 15 mg/kg
12
38820
026741-53-7
Bis (2,4-di-tert-butylphenyl) pentaery-thritol diphosphite
SML = 0.6 mg/kg
13
39060
035958-30-6
1,1-Bis (2-hydroxy-3, 5-di-tert-butylphenyl) ethane
SML = 5 mg/kg
14
39090
N,N-bis (2-hydroxyethyl) alkyl (C8-C18) amine
SML(T) = 1.2 mg/kg (12)
15
39120
N,N-bis (2-hydroxyethyl)-alkyl (C8-C18) amine hydrochlorides
SML(T) = 1.2 mg/kg (12) expressed as tertiary amine (expressed excluding HCI)
16
40000
000991-84-4
2,4-Bis (octylmercapto) – 6- (4-hydroxy- 3,5,di-tert-butylanilino) - 1,3,5-triazine
SML = 30 mg/kg
17
40020
110553-27-0
2,4-Bis (octylthiomethyl) – 6- methylphenol
SML = 6 mg/kg
18
40160
061269-61-2
N,N'-bis (2,2,6,6-tetramethyl-4- piperidyl) hexamethy-lenediamine- 1,2- dibromoethane, copolymer
SML = 2.4 mg/kg
18A
40720
025013-16-5
Tert-butyl- 4-hydroxyanisole (= BHA)
SML = 30 mg/kg
19
40800
013003-12-8
4,4' – butylidene-bis (6-tert-butyl-3-methylphenyl-ditridecyl phosphite)
SML = 6 mg/kg
20
409080
019664-95-0
Butyric acid, manganese salt
SML(T) = 0.6 mg/kg (9) (expressed as manganese)
21
42000
063438-80-2
(2-carbobutoxyethyl) tin-tris (isooctyl mercaptoacetate)
SML = 30 mg/kg
22
42400
010377-37-4
Carbonic acid, lithium salt
SML(T) = 0.6 mg/kg (8) (expressed as lithium)
23
42480
000584-09-8
Carbonic acid, rubidium salt
SML = 12 mg/kg
24
43600
004080-31-3
1- (3- Chloroallyl) – 3,5,7 – triaza-1-azoniaadamantane chloride
SML = 0.3 mg/kg
25
43680
000075-45-6
Chlorodifluoromethane
SML = 6 mg/kg and in compliance with the specifications laid down in Schedule 4
26
44960
011104-61-3
Cobalt oxide
SML(T) = 0.05 mg/kg (13) (expressed as cobalt)
27
45440
-
Cresols, butylated, styrenated
SML = 12 mg/kg
27A
45650
006197-30-4
2-Cyano-3,3-diphenylacrylic acid, 2-ethylhexyl ester
SML = 0.05 mg/kg
27B
46640
000128-37-0
2,6-di-tert-butyl-p-cresol (= BHT)
SML = 3.0 mg/kg
29
47600
084030-61-5
Di-n-dodecyltin bis (isooctyl mercaptoacetate)
SML = 12 mg/kg
30
48640
000131-56-6
2,4-Dihydroxybenzophenone
SML(T) = 6 mg/kg (14)
31
48800
000097-23-4
2,2'-Dihydroxy-5,5'-dichlorodiphenylmethane
SML = 12 mg/kg
32
48880
000131-53-3
2,2'Dihydroxy-4-methoxybenzophenone
SML(T) = 6 mg/kg (14)
33
49600
026636-01-1
Dimethyltin bis (isooctyl mercaptoaecetate)
SMT(T) 0.18 mg/kg (15) (expressed as tin)
34
49840
002500-88-1
Dioctadecyl disulphide
SMT = 3 mg/kg
35
50160
Di-n-octyltin bis(n-alkyl (C10-C16) mercaptoacetate)
SML(T) = 0.04 mg/kg (16) (expressed as tin)
36
50240
010039-33-5
Di-n-octyltin bis (2-ethylhexyl maleate)
SML(T) = 0.04 mg/kg (16) (expressed as tin)
37
50320
015571-58-1
Di-n-octyltin bis (2-ethylhexyl mercaptoaectate)
SML(T) = 0.04 mg/kg (16) (expressed as tin)
38
50360
Di-n-octyltin bis (ethyl maleate)
SML(T) = 0.04 mg/kg (16) (expressed as tin)
39
50400
033568-99-9
Di-n-octyltin bis (isooctyl maleate)
SML(T) = 0.04 mg/kg (16) (expressed as tin)
40
50480
026401-97-8
Di-n-octyltin bis (isooctyl mercaptoacetate)
SML(T) = 0.04 mg/kg (16) (expressed as tin)
41
50560
Di-n-octyltin 1,4-butanediol bis (mercaptoacetate)
SML(T) = 0.04 mg/kg (16) (expressed as tin)
42
50640
003648-18-8
Di-n-octyltin dilaurate
SML(T) = 0.04 mg/kg (16) (expressed as tin)
43
50720
015571-60-5
Di-n-octyltin dimaleate
SML(T) = 0.04 mg/kg (16) (expressed as tin)
44
50800
-
Di-n-octyltin dimaleate, esterified
SML(T) = 0.04 mg/kg (16) (expressed as tin)
45
50880
-
Di-n-octyltin dimaleate, polymers (n = 2-4)
SML(T) = 0.04 mg/kg (16) (expressed as tin)
46
50960
069226-44-4
Di-n-octyltin ethyleneglycol bis (mercaptoacetate)
SML(T) = 0.04 mg/kg (16) (expressed as tin)
47
51040
015535-79-2
Di-n-octyltin mercaptoacetate
SML(T) = 0.04 mg/kg (16) (expressed as tin)
48
51120
Di-n-octyltin thiobenzoate 2-ethyl-hexyl mercaptoacetate
SML(T) = 0.04 mg/kg (16) (expressed as tin)
49
51570
000127-63-9
Diphenyl sulphone
SML(T) = 3 mg/kg (24)
50
51680
000102-08-9
N,N'-diphenylthiourea
SML = 3 mg/kg
51
52000
027176-87-0
Dodecylbenzenesulphonic acid
SML = 30 mg/kg
52
52320
052047-59-3
2-(4-Dodecylphenyl) indole
SML = 0.06 mg/kg
53
52880
023676-09-7
4-Ethoxybenzoic acid, ethyl ester
SML = 3.6 mg/kg
54
53200
023949-66-8
2-Ethoxy-2'-ethyloxanilide
SML = 30 mg/kg
54A
54880
000050-00-0
Formaldehyde
SML(T) = 15 mg/kg (21)
54B
55200
001166-52-5
Gallic acid, dodecyl ester
SML(T) = 30 mg/kg (34)
54C
55280
001034-01-1
Gallic acid, octyl ester
SML(T) = 30 mg/kg (34)
54D
55360
000121-79-9
Gallic acid, propyl ester
SML(T) = 30 mg/kg (34)
55
58960
000057-09-0
Hexadecyltrimethylammonium bromide
SML = 6 mg/kg
56
59120
023128-74-7
1,6-Hexamethylene-bis (3- (3,5-di-tert-butyl-4-hydroxyphenyl) propionamide)
SML = 45 mg/kg
57
59200
035074-77-2
1,6- Hexamethylene-bis (3- (3,5-di-tert-butyl-4-hydroxyphenyl) propionate
SML = 6 mg/kg
58
60320
070321-86-7
2- (2-Hydroxy-3,5-bis (1,1-dimethylbenzyl) phenyl) benzotriazole
SML = 1.5 mg/kg
59
60400
003896-11-5
2- (2'-Hydroxy-3'-tert-butyl- 5'-methylphenyl) –5-chlorobenzotriazole
SML(T) = 30 mg./kg (18)
60
60800
065447-77-0
1-(2- Hydroxyethyl) –4-hydroxy- 2,2, 6,6-tetramethyl, piperidine-succinic acid, dimethyl ester, copolymer
SML = 30 mg/kg
61
61280
003293-97-8
2-Hydroxy-4-n-hexyloxybenzophenone
SML(T) = 6 mg/kg (14)
62
61360
000131-57-7
2-Hydroxy-4-methoxybenzophenone
SML(T) = 6 mg/kg (14)
63
61440
002440-22-4
2-(2-Hydroxy-5-methylphenyl) benzotriazole
SML(T) = 30 mg/kg (18)
64
61600
001843-05-6
2-Hydroxy-4-n-octyloxybenzophenone
SML(T) = 6 mg/kg (14)
65
63200
051877-53-3
Lactic acid, manganese salt
SML(T) = 0.6 mg/kg (9) (expressed as manganese)
66
64320
010377-51-2
Lithium iodide
SML(T) = 1 mg/kg (10) (expressed as iodium) and SML(T) = 0.6 mg/kg (8) (expressed as lithium)
67
65120
007773-01-5
Manganese chloride
SML(T) = 0.6 mg/kg (9) (expressed as manganese)
68
65200
012626-88-9
Manganese hydroxide
SML(T) = 0.6 mg/kg (9) (expressed as manganese
69
65280
010043-84-2
Manganese hypophosphite
SML(T) = 0.6 mg/kg (9) (expressed as manganese
70
65360
011129-60-5
Manganese oxide
SML(T) = 0.6 mg/kg (9) (expressed as manganese
71
65440
Manganese pyrophosphite
SML(T) = 0.6 mg/kg (9) (expressed as manganese
72
66360
085209-91-2
2-2'-Methylene bis (4,6-di-tert-butylphenyl) sodium phosphate
SML = 5 mg/kg
73
66400
000088-24-4
2-2'-Methylene bis (4-ethyl-6-tert-butylphenol)
SML(T) = 1.5 mg/kg (19)
74
66480
000119-47-1
2-2'-Methylene bis (4-methyl-6-tert-butylphenol)
SML(T) = 1.5 mg/kg (19)
75
67360
067649-65-4
Mono-n-dodecyltin tris (isooctyl mercaptoacetate)
SML = 24 mg/kg
76
67520
054849-38-6
Monomethyltin tris (isooctyl mercaptoacetate)
SML(T) = 0.18 mg/kg (15) (expressed as tin)
77
67600
Mono-n-octyltin tris (alkyl (C10-C16) - mercaptoacetate
SML(T) = 1.2 mg/kg (17) (expressed as tin)
78
67680
027107-89-7
Mono-n-octyltin tris (2-ethylhexyl mercaptoacetate
SML(T) = 1.2 mg/kg (17) (expressed as tin)
79
67760
026401-86-5
Mono-n-octyltin tris (isooctyl mercaptoacetate)
SML(T) = 1.2 mg/kg (17) (expressed as tin)
79A
67896
020336-96-3
Myristic acid, lithium salt
SML(T) = 0.6 mg/kg (8) (expressed as lithium)
81
68320
002082-79-3
Octadecyl 3- (3,5-di-tert-butyl-4- hydroxylphenyl) propionate
SML = 6 mg/kg
82
68400
010094-45-8
Octadecylerucamide
SML = 5 mg/kg
82A
68860
004724-48-5
n-Octylphosphonic acid
SML = 0.05 mg/kg
83
69840
016260-09-6
Oleylpalmitamide
SML = 5 mg/kg
83A
71935
007601-89-0
Perchloric acid, sodium salt monohydrate
SML = 0.05 mg/kg (31)
84
72160
000948-65-2
2-Phenylindole
SML = 15 mg/kg
85
72800
001241-94-7
Phosphoric acid, diphenyl 2-ethylhexyl ester
SML = 2.4 mg/kg
86
73040
013763-32-1
Phosphoric acid, lithium salts
SML(T) = 0.6 mg/kg (8) (expressed as lithium)
87
73120
010124-54-6
Phosphoric acid, manganese salt
SML(T) = 0.6 mg/kg (9) (expressed as manganese)
88
74400
Phosphorous acid, tris (nonyl- and/or dinonylphenyl) ester
SML = 30 mg/kg
88A
76680
068132-00-3
Polycyclopentadiene, hydrogenated
SML = 5 mg/kg (1)
89
77440
Polyethyleneglycol diricinoleate
SML = 42 mg/kg
90
77520
061791-12-6
Polyethyleneglycol ester of caster oil
SML = 42 mg/kg
91
78320
009004-97-1
Polyethyleneglycol monoricinoleate
SML – 42 mg/kg
92
81200
071878-19-8
Poly [6- [1,1,3,3- tetramethylbutyl) – amino]- 1,3,5-triazine-2,4-diyl]- [(2,2,6,6-tetramethyl- 4-piperidyl)-imino] hexamethylene- [2,2,6,6-tetramethyl-4-piperidyl) imino]
SML = 3 mg/kg
93
81680
007681-11-0
Potassium iodide
SML(T) = 1 mg/kg (10) (expressed as iodium)
94
82020
019019-51-3
Propionic acid, cobalt salt
SML(T) = 0.05 mg/kg (13) (expressed as cobalt)
95
83595
119345-01-6
Reaction product of di-tert-butylphosphonite with biphenyl, obtained by condensation of 2,4-di-tert-butylphenol with Friedel Craft reaction product of phosphorus trichloride and biphenyl
SML = 18 mg/kg and in compliance with the specifications in Schedule 4
96
83700
000141-22-0
Ricinoleic acid
SML = 42 mg/kg
97
84800
000087-18-3
Salicylic acid, 4-tert-butylphenyl ester
SML = 12 mg/kg
98
84880
000119-36-8
Salicylic acid, methyl ester
SML = 30 mg/kg
99
85760
012068-40-5
Silicic acid, lithium aluminium salt (2:1:1)
SML(T) = 0.6 mg/kg (8) (expressed as lithium)
100
85920
012627-14-4
Silicic acid, lithium salt
SML(T) = 0.6 mg/kg (8) (expressed as lithium)
100A
86480
007631-90-5
Sodium bisulphite
SML(T) = 10 mg/kg (30) (expressed as SO2)
101
86800
007681-82-5
Sodium iodide
SML(T) = 1 mg/kg (10) (expressed as iodium)
102
86880
Sodium monoalkyl dialkylphenoxybenzenedi-sulphonate
SML = 9 mg/kg
102A
86920
007632-00-0
Sodium nitrite
SML = 0.6 mg/kg
102B
86960
007757-83-7
Sodium sulphite
SML(T) = 10 mg/kg (30) (expressed as SO2)
102C
87120
007772-98-7
Sodium thiosulphate
SML(T) = 10 mg/kg (30) (expressed as SO2)
103
89170
013586-84-0
Stearic acid, cobalt salt
SML(T) = 0.05 mg/kg (13) (expressed as cobalt)
104
92000
007727-43-7
Sulphuric acid, barium salt
SML(T) = 1 mg/kg (11) (expressed as barium)
105
92320
Tetradecyl-polyethyleneglycol (EO = 3-8) ether of glycolic acid
SML = 15 mg/kg
106
92560
038613-77-3
Tetrakis (2,4- di-tert-butyl-phenyl) – 4-4' –biphenylylene diphosphonite
SML = 18 mg/kg
107
92800
000096-69-5
4,4'-Thiobis (6-tert-butyl- 3-methylphenol)
SML = 0.48 mg/kg
108
92880
041484-35-9
Thiodiethanol bis (3-(3-5-di-tert- butyl-4-hydroxyphenyl) propionate)
SML = 2.4 mg/kg
109
93120
000123-28-4
Thiodipropionic acid, didodecyl ester
SML(T) = 5 mg/kg (20)
110
93280
000693-36-7
Thiodipropionic acid, dioctadecyl ester
SML(T) = 5 mg/kg (20)
110A
94400
036443-68-2
Triethyleneglycol bis[ 3-(3-tert-butyl- 4-hydroxy- 5-methylphenyl) propionate]
SML = 9 mg/kg
111
94560
000122-20-3
Triisopropanolamine
SML = 5 mg/kg
112
95280
040601-76-1
1,3,5- Tris (4-tert-butyl-3-hydroxy –2,6- dimethylbenzyl)- 1,3,5-triazine-2,4,6 (1H, 3H,5H)- trione
SML = 6 mg/kg
113
95360
027676-62-6
1,3,5 – Tris (3,5-di-tert-butyl-4 hydroxybenzyl)- 1,3,5-triazine –2,4,6 (1H, 3H, 5H) - trione
SML = 5 mg/kg
114
95600
001843-03-4
1,1,3- Tris (2-methyl-4-hydroxy-5-tert-butylphenyl) butane
SML = 5 mg/kg

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Source: https://www.legislation.gov.uk/uksi/2006/1401/schedule/2/part/2 (the official version)
Page: https://openlegislation.uk/plastic-materials-and-articles-in-contact-with-food-england-regulations-2006/schedule-2/part-2
Contains public sector information licensed under the Open Government Licence v3.0. Source: legislation.gov.uk, The National Archives.