Division 25
United Kingdom
BAT is to reduce NOX emissions from the melting furnace by using one or a combination of the following techniques:
- I..
primary techniques, such as:
A description of the techniques is given in Section 1.10.2.
Techniquef1 Applicability (i) Combustion modifications (a)
Reduction of air/fuel ratio
Applicable to air/fuel conventional furnaces.
Full benefits are achieved at normal or complete furnace rebuild, when combined with optimum furnace design and geometry
(b)
Reduced combustion air temperature
The applicability is restricted to small capacity furnaces for the production of specialty flat glass and under installation-specific circumstances, due to a lower furnace efficiency and higher fuel demand (i.e. use of recuperative furnaces in place of regenerative furnaces) (c)
Staged combustion:
-
Air staging
-
Fuel staging
Fuel staging is applicable to most conventional air/fuel furnaces.
Air staging has very limited applicability due to its technical complexity
(d)
Flue-gas recirculation
The applicability of this technique is limited to the use of special burners with automatic recirculation of the waste gas (e)
Low-NOX burners
The technique is generally applicable.
The achieved environmental benefits are generally lower for applications to cross-fired, gas-fired furnaces due to technical constraints and a lower degree of flexibility of the furnace.
Full benefits are achieved at normal or complete furnace rebuild, when combined with optimum furnace design and geometry
(f)
Fuel choice
The applicability is limited by the constraints associated with the availability of different types of fuel, which may be impacted by the energy policy of the Member State (ii)
Fenix process
Based on the combination of a number of primary techniques for the optimisation of the combustion of cross-fired regenerative float furnaces. The main features are:
-
reduction of excess air
-
suppression of hotspots and homogenisation of the flame temperatures
-
controlled mixing of the fuel and combustion air
The applicability is limited to cross-fired regenerative furnaces.
Applicable to new furnaces.
For existing furnaces, the technique requires being directly integrated during the design and construction of the furnace, at a complete furnace rebuild
(iii)
Oxy-fuel melting
The maximum environmental benefits are achieved for applications at the time of a complete furnace rebuild -
- II..
secondary techniques, such as:
A description of the techniques is given in Section 1.10.2.
Techniquef2 Applicability (i)
Chemical reduction by fuel
Applicable to regenerative furnaces.
The applicability is limited by an increased fuel consumption and consequent environmental and economic impact
(ii)
Selective catalytic reduction (SCR)
The application may require an upgrade of the dust abatement system in order to guarantee a dust concentration of below 10 – 15 mg/Nm3 and a desulphurisation system for the removal of SOX emissions
Due to the optimum operating temperature window, the applicability is limited to the use of electrostatic precipitators. In general, the technique is not used with a bag filter system because the low operating temperature, in the range of 180 – 200 °C, would require reheating of the waste gases.
The implementation of the technique may require significant space availability
Table 15
BAT-AELs for NOX emissions from the melting furnace in the flat glass sector
| Higher emission levels are expected when nitrates are used occasionally for the production of special glasses. | |||
| The conversion factor reported in Table 2 (2,5 × 10–3) has been applied. | |||
| The lower levels of the range are associated with the application of the Fenix process. | |||
| The achievable levels depend on the quality of the natural gas and oxygen available (nitrogen content). | |||
| The higher levels of the range are associated with existing plants until a normal or complete rebuild of the melting furnace. The lower levels are associated with newer/retrofitted plants. | |||
| Parameter | BAT | BAT-AELf3 | |
|---|---|---|---|
| mg/Nm3 | kg/tonne melted glassf4 | ||
| NOX expressed as NO2 | Combustion modifications, Fenix processf5 | 700 – 800 | 1,75 – 2,0 |
| Oxy-fuel meltingf6 | Not applicable | < 1,25 – 2,0 | |
| Secondary techniquesf7 | 400 – 700 | 1,0 – 1,75 | |
Annotations
Footnotes
- f1
-
A description of the techniques is given in Section 1.10.2.
- f2
-
A description of the techniques is given in Section 1.10.2.
- f3
-
Higher emission levels are expected when nitrates are used occasionally for the production of special glasses.
- f4
-
The conversion factor reported in Table 2 (2,5 × 10–3) has been applied.
- f5
-
The lower levels of the range are associated with the application of the Fenix process.
- f6
-
The achievable levels depend on the quality of the natural gas and oxygen available (nitrogen content).
- f7
-
The higher levels of the range are associated with existing plants until a normal or complete rebuild of the melting furnace. The lower levels are associated with newer/retrofitted plants.