Division BAT 56 In order to prevent or reduce NOX emissions to air while limiting CO emissions to air from the combustion of process fuels from the chemical industry, BAT is to use one or a combination of the techniques given below.
United Kingdom
| Technique | Description | Applicability | |
|---|---|---|---|
| a. | Low-NOX burners (LNB) | See descriptions in Section 8.3 | Generally applicable |
| b. | Air staging | ||
| c. | Fuel staging | See description in Section 8.3. Applying fuel staging when using liquid fuel mixtures may require a specific burner design | |
| d. | Flue-gas recirculation | See descriptions in Section 8.3 | Generally applicable to new combustion plants. Applicable to existing combustion plants within the constraints associated with chemical installation safety |
| e. | Water/steam addition | The applicability may be limited due to water availability | |
| f. | Fuel choice | Applicable within the constraints associated with the availability of different types of fuel and/or an alternative use of the process fuel | |
| g. | Advanced control system | The applicability to old combustion plants may be constrained by the need to retrofit the combustion system and/or control command system | |
| h. | Selective non-catalytic reduction (SNCR) | Applicable to existing combustion plants within the constraints associated with chemical installation safety. Not applicable to combustion plants operated < 500 h/yr. The applicability may be limited in the case of combustion plants operated between 500 h/yr and 1 500 h/yr with frequent fuel changes and frequent load variations | |
| i. | Selective catalytic reduction (SCR) | Applicable to existing combustion plants within the constraints associated with duct configuration, space availability and chemical installation safety. Not applicable to combustion plants operated < 500 h/yr. There may be technical and economic restrictions for retrofitting existing combustion plants operated between 500 h/yr and 1 500 h/yr. Not generally applicable to combustion plants of < 100 MWth | |
Table 34
BAT-associated emission levels (BAT-AELs) for NOX emissions to air from the combustion of 100 % process fuels from the chemical industry in boilers
| For plants operated < 1 500 h/yr, these BAT AELs do not apply. | ||||
| For plants operated < 500 h/yr, these levels are indicative. | ||||
| For existing plants of ≤ 500 MWth put into operation no later than 27 November 2003 using liquid fuels with a nitrogen content higher than 0,6 wt-%, the higher end of the BAT-AEL range is 380 mg/Nm3. | ||||
| For existing plants put into operation no later than 7 January 2014, the higher end of the BAT-AEL range is 180 mg/Nm3. | ||||
| For existing plants put into operation no later than 7 January 2014, the higher end of the BAT-AEL range is 210 mg/Nm3. | ||||
| Fuel phase used in the combustion plant | BAT-AELs (mg/Nm3) | |||
|---|---|---|---|---|
| Yearly average | Daily average or average over the sampling period | |||
| New plant | Existing plantf1 | New plant | Existing plantf2 | |
| Mixture of gases and liquids | 30–85 | 80–290f3 | 50–110 | 100–330 |
| Gases only | 20–80 | 70–100f4 | 30–100 | 85–110f5 |
As an indication, the yearly average CO emission levels for existing plants operated ≥ 1 500 h/yr and for new plants will generally be < 5–30 mg/Nm3.
Annotations
Footnotes
- f1
-
For plants operated < 1 500 h/yr, these BAT AELs do not apply.
- f2
-
For plants operated < 500 h/yr, these levels are indicative.
- f3
-
For existing plants of ≤ 500 MWth put into operation no later than 27 November 2003 using liquid fuels with a nitrogen content higher than 0,6 wt-%, the higher end of the BAT-AEL range is 380 mg/Nm3.
- f4
-
For existing plants put into operation no later than 7 January 2014, the higher end of the BAT-AEL range is 180 mg/Nm3.
- f5
-
For existing plants put into operation no later than 7 January 2014, the higher end of the BAT-AEL range is 210 mg/Nm3.