Division BAT 57 In order to reduce SOX, HCl and HF emissions to air from the combustion of process fuels from the chemical industry in boilers, BAT is to use one or a combination of the techniques given below.
United Kingdom
| Technique | Description | Applicability | |
|---|---|---|---|
| a. | Fuel choice | See descriptions in Section 8.4 | Applicable within the constraints associated with the availability of different types of fuel and/or an alternative use of the process fuel |
| b. | Boiler sorbent injection (in-furnace or in-bed) | Applicable to existing combustion plants within the constraints associated with duct configuration, space availability and chemical installation safety. Wet FGD and seawater FGD are not applicable to combustion plants operated < 500 h/yr. There may be technical and economic restrictions for applying wet FGD or seawater FGD to combustion plants of < 300 MWth, and for retrofitting combustion plants operated between 500 h/yr and 1 500 h/yr with wet FGD or seawater FGD | |
| c. | Duct sorbent injection (DSI) | ||
| d. | Spray dry absorber (SDA) | ||
| e. | Wet scrubbing | See description in Section 8.4. Wet scrubbing is used to remove HCl and HF when no wet FGD is used to reduce SOX emissions | |
| f. | Wet flue-gas desulphurisation (wet FGD) | See descriptions in Section 8.4 | |
| g. | Seawater FGD | ||
Table 35
BAT-associated emission levels (BAT-AELs) for SO2 emissions to air from the combustion of 100 % process fuels from the chemical industry in boilers
| For existing plants operated < 1 500 h/yr, these BAT-AELs do not apply. | ||
| For existing plants operated < 500 h/yr, these levels are indicative. | ||
| Type of combustion plant | BAT-AELs (mg/Nm3) | |
|---|---|---|
| Yearly averagef1 | Daily average or average over the sampling periodf2 | |
| New and existing boilers | 10–110 | 90–200 |
Table 36
BAT-associated emission levels (BAT-AELs) for HCl and HF emissions to air from the combustion of process fuels from the chemical industry in boilers
| For plants operated < 500 h/yr, these levels are indicative. | ||||
| In the case of plants operated < 1 500 h/yr, the higher end of the BAT-AEL range is 20 mg/Nm3. | ||||
| In the case of plants operated < 1 500 h/yr, the higher end of the BAT-AEL range is 7 mg/Nm3. | ||||
| Combustion plant total rated thermal input(MWth) | BAT-AELs (mg/Nm3) | |||
|---|---|---|---|---|
| HCl | HF | |||
| Average of samples obtained during one year | ||||
| New plant | Existing plantf3 | New plant | Existing plant | |
| < 100 | 1–7 | 2–15f4 | < 1–3 | < 1–6f5 |
| ≥ 100 | 1–5 | 1–9 | < 1–2 | < 1–3 |
Annotations
Footnotes
- f1
-
For existing plants operated < 1 500 h/yr, these BAT-AELs do not apply.
- f2
-
For existing plants operated < 500 h/yr, these levels are indicative.
- f3
-
For plants operated < 500 h/yr, these levels are indicative.
- f4
-
In the case of plants operated < 1 500 h/yr, the higher end of the BAT-AEL range is 20 mg/Nm3.
- f5
-
In the case of plants operated < 1 500 h/yr, the higher end of the BAT-AEL range is 7 mg/Nm3.